Size-dependent bandgap and particle size distribution of colloidal semiconductor nanocrystals

A new analytical expression for the size-dependent bandgap of colloidal semiconductor nanocrystals is proposed within the framework of the finite-depth square-well effective mass approximation in order to provide a quantitative description of the quantum confinement effect. This allows one to convert optical spectroscopic data (photoluminescence spectrum and absorbance edge) into accurate estimates for the particle size distributions of colloidal systems even if the traditional effective mass model is expected to fail, which occurs typically for very small particles belonging to the so-called strong confinement limit. By applying the reported theoretical methodologies to CdTe nanocrystals synthesized through wet chemical routes, size distributions are inferred and compared directly to those obtained from atomic force microscopy and transmission electron microscopy. This analysis can be used as a complementary tool for the characterization of nanocrystal samples of many other systems such as the II-VI and III-V semiconductor materials.Comment: 9 pages, 5 figure

Time Dependent Development of the Coulomb Gap

We show that the time development of the Coulomb gap in a Coulomb glass can involve very long relaxation times due to electron rearrangement and hopping. We find that an applied magnetic field reduces the rate of electron hopping and, hence, Coulomb gap formation. These results are consistent with recent conductance experiments on thin semiconducting and metallic films.Comment: 4 pages, Latex, 3 encapsulated postscript figure

Spontaneous emission from large quantum dots in nanostructures: exciton-photon interaction beyond the dipole approximation

We derive a rigorous theory of the interaction between photons and spatially extended excitons confined in quantum dots in inhomogeneous photonic materials. We show that, beyond the dipole approximation, the radiative decay rate is proportional to a non-local interaction function, which describes the interaction between light and spatially extended excitons. In this regime, light and matter degrees of freedom cannot be separated and a complex interplay between the nanostructured optical environment and the exciton envelope function emerges. We illustrate this by specific examples and derive a series of important analytical relations, which are useful for applying the formalism to practical problems. In the dipole limit, the decay rate is proportional to the projected local density of optical states and we obtain the strong and weak confinement regimes as special cases.Comment: 14 pages, 4 figure

Scaling near the upper critical dimensionality in the localization theory

The phenomenon of upper critical dimensionality d_c2 has been studied from the viewpoint of the scaling concepts. The Thouless number g(L) is not the only essential variable in scale transformations, because there is the second parameter connected with the off-diagonal disorder. The investigation of the resulting two-parameter scaling has revealed two scenarios, and the switching from one to another scenario determines the upper critical dimensionality. The first scenario corresponds to the conventional one-parameter scaling and is characterized by the parameter g(L) invariant under scale transformations when the system is at the critical point. In the second scenario, the Thouless number g(L) grows at the critical point as L^{d-d_c2}. This leads to violation of the Wegner relation s=\nu(d-2) between the critical exponents for conductivity (s) and for localization radius (\nu), which takes the form s=\nu(d_c2-2). The resulting formulas for g(L) are in agreement with the symmetry theory suggested previously [JETP 81, 925 (1995)]. A more rigorous version of Mott's argument concerning localization due topological disorder has been proposed.Comment: PDF, 7 pages, 6 figure